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Triarylpyridinium salts: Synthesis and electrochemical properties
Author(s) -
Dolganov Alexandr V.,
Tanaseichuk Boris S.,
Pryanichnikova Margarita K.,
Ivleva Alina Y.,
Chernyaeva Oksana Y.,
Grigoryan Karina A.,
Chugunova Ekaterina A.,
Yurova Veronika Y.
Publication year - 2019
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.3930
Subject(s) - chemistry , electrochemistry , acetonitrile , redox , electron transfer , ion , reduction (mathematics) , inorganic chemistry , combinatorial chemistry , photochemistry , organic chemistry , electrode , geometry , mathematics
The electrochemical properties of the triarylpyridinium salts were studied. The effect of functional substituents on redox properties has been investigated in detail. Electrochemical reduction of salts to the anion in acetonitrile is the result of two one‐electron‐transfer steps through the stage of the radical formation and its subsequent reduction (EE electrochemical mechanism). A correlation between the reduction potentials and the structure of the salts was established.