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Functionalization of oxabenzonorbornadiene: Manganese(III)‐mediated oxidative addition of dimedone
Author(s) -
Çalışkan Raşit,
Sari Ozlem,
Balci Metin
Publication year - 2017
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.3720
Subject(s) - dimedone , chemistry , ring (chemistry) , manganese , acetic acid , medicinal chemistry , reaction mechanism , manganese(iii) acetate , surface modification , organic chemistry , catalysis
The reaction of oxabenzonorborna‐diene with dimedone and Mn(OAc) 3 in the presence of HCl gave an adduct that was submitted to the ring‐opening reactions. The BBr 3 ‐supported ring‐opening reaction of the adduct gave a five‐membered ring, however, reaction with formed a bicyclic system.
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