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Solid‐state bilayer formation from a dialkyl‐substituted lariat ether that forms stable vesicles in aqueous suspension
Author(s) -
Wall Stephen L. De,
Barbour Leonard J.,
Gokel George W.
Publication year - 2001
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.369
Subject(s) - chemistry , vesicle , bilayer , ether , suspension (topology) , aqueous solution , solid state , crown ether , polymer chemistry , alkyl , crystallography , stereochemistry , organic chemistry , membrane , ion , biochemistry , mathematics , homotopy , pure mathematics
Previously established aggregate formation by alkyl‐substituted crown ethers is considered with respect to the solid state structure of N , N ′‐didodecyldiaza‐18‐crown‐6 ( 7 ), which was determined as its NaI complex ( 7 ċNaIċH 2 O). The complex forms a bilayer structure that was used as a benchmark for understanding the formation of aggregates and their inclusion volumes. Copyright © 2001 John Wiley & Sons, Ltd.