Paternò–Büchi  photochemical  [2 + 2]  cycloaddition  of aromatic carbonyl compounds with 2‐siloxy‐1 H ‐pyrrole derivatives | Zendy

Xue Jianfei | Zendy; Abe Manabu | Zendy; Takagi Ryukichi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Paternò–Büchi photochemical [2 + 2] cycloaddition of aromatic carbonyl compounds with 2‐siloxy‐1 H ‐pyrrole derivatives

Author(s) -

Xue Jianfei,

Abe Manabu,

Takagi Ryukichi

Publication year - 2017

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.3632

Subject(s) - regioselectivity , chemistry , oxetane , benzophenone , pyrrole , cycloaddition , bicyclic molecule , medicinal chemistry , photochemistry , stereochemistry , organic chemistry , catalysis

The purpose of this study was to explore regioselectivity and stereoselectivity in the Paternò–Büchi reaction of pyrrole derivatives. The regioselective formation of a bicyclic oxetane in the Paternò–Büchi reaction of 2‐siloxypyrrole with benzophenone was reported for the first time, and a mechanism involving the distribution of the intermediary triplet diradicals was proposed to account for the regioselectivity of the reaction. Copyright © 2016 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research