Dramatic solvent and concentration dependence in the reaction of (anthracen‐9‐yl)methanamines with suitable electron‐deficient acetylenes | Zendy

Jacob Jomon P. | Zendy; Gopalakrishnan Reshma | Zendy; Mallia Rekha R. | Zendy; Vadakkan Jean John | Zendy; Unnikrishnan Perupparampil A. | Zendy; Prathapan Sreedharan | Zendy

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Dramatic solvent and concentration dependence in the reaction of (anthracen‐9‐yl)methanamines with suitable electron‐deficient acetylenes

Author(s) -

Jacob Jomon P.,

Gopalakrishnan Reshma,

Mallia Rekha R.,

Vadakkan Jean John,

Unnikrishnan Perupparampil A.,

Prathapan Sreedharan

Publication year - 2014

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.3351

Subject(s) - chemistry , reactivity (psychology) , solvent , electron transfer , solvent effects , organic solvent , electron , medicinal chemistry , computational chemistry , photochemistry , organic chemistry , chemical engineering , medicine , physics , alternative medicine , pathology , quantum mechanics , engineering

Herein, we describe diverse reactivity of (anthracen‐9‐yl)methanamines with a few electron‐deficient acetylenes. Depending on the solvent and concentration, (anthracen‐9‐yl)methanamines reacted with acetylenes through one electron transfer, two electron transfer, or Diels–Alder pathways; and under certain conditions, we observed multiple reaction pathways. We have proposed plausible mechanisms to account for various reactions observed by us. Copyright © 2014 John Wiley & Sons, Ltd.

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