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Reactivity studies of carbon, phosphorus and sulfur‐based acyl sites with tertiary oximes in gemini surfactants
Author(s) -
Gupta Bhanushree,
Sharma Rahul,
Singh Namrata,
Karpichev Yevgen,
Satnami Manmohan L.,
Ghosh Kallol K.
Publication year - 2013
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.3142
Subject(s) - chemistry , reaction rate constant , carboxylate , reactivity (psychology) , medicinal chemistry , sulfonate , micelle , organic chemistry , toluene , phosphate , nucleophile , aqueous solution , inorganic chemistry , kinetics , catalysis , sodium , medicine , physics , alternative medicine , pathology , quantum mechanics
Kinetic studies of the reactions of tertiary oximes (monoisonitroso acetone; MINA and butane 2,3 dione monooxime; BDMO) with some carboxylate ( p ‐nitrophenyl acetate and p ‐nitrophenyl benzoate), phosphate ( p ‐nitrophenyl diphenyl phosphate and bis (2,4‐dinitrophenyl) phosphate) and sulfonate ( p ‐nitrophenyl p ‐toluene sulphonate) esters in gemini surfactants have been conducted. The observed first‐order rate constant versus surfactant profiles show micelle‐assisted bimolecular reactions involving interfacial ion exchange between bulk aqueous media and micellar pseudophase. Experimental results showed that MINA exhibited better nucleophilic activity towards ester cleavage than BDMO. Pseudophase model has been applied in order to determine micellar second‐order rate constants and binding constants. Copyright © 2013 John Wiley & Sons, Ltd.