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Effect of aromaticity on the rate of azaquinone methide‐mediated release of benzylic phenols
Author(s) -
Schmid Kyle M.,
Phillips Scott T.
Publication year - 2013
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.3129
Subject(s) - chemistry , aromaticity , phenols , quinone methide , polymer , organic chemistry , molecule , quinone
Herein we use small molecule models of stimuli‐induced degradable/depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide‐mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units. Copyright © 2013 John Wiley & Sons, Ltd.
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