Synthesis, UV–Vis and CV properties of a structurally related series of bis(Arylimino)acenaphthenes (Ar‐BIANs) | Zendy

Hasan Kamrul | Zendy; ZysmanColman Eli | Zendy

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Synthesis, UV–Vis and CV properties of a structurally related series of bis(Arylimino)acenaphthenes (Ar‐BIANs)

Author(s) -

Hasan Kamrul,

ZysmanColman Eli

Publication year - 2013

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.3081

Subject(s) - acenaphthene , chemistry , aryl , electrochemistry , polymerization , catalysis , photochemistry , series (stratigraphy) , organic chemistry , alkyl , polymer , electrode , anthracene , paleontology , biology

Herein, we report the synthesis and electrochemical and spectroscopic characterization for a series of six bis(arylimino)acenaphthene, compounds commonly used as ligands in catalysis , polymerization and materials. Low energy absorption bands are the result of an intraligand charge transfer between the aryl groups and the acenaphthene core, and their energies obey a Hammett relationship with respect to substitution on the aryl. Copyright © 2013 John Wiley & Sons, Ltd.

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