Adamantyl‐endcapped polyynes | Zendy

Chalifoux Wesley A. | Zendy; Ferguson Michael J. | Zendy; McDonald Robert | Zendy; Melin Frederic | Zendy; Echegoyen Luis | Zendy; Tykwinski Rik R. | Zendy

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Adamantyl‐endcapped polyynes

Author(s) -

Chalifoux Wesley A.,

Ferguson Michael J.,

McDonald Robert,

Melin Frederic,

Echegoyen Luis,

Tykwinski Rik R.

Publication year - 2012

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1874

Subject(s) - chemistry , differential scanning calorimetry , cyclic voltammetry , spectroscopy , nuclear magnetic resonance spectroscopy , polymer chemistry , crystallography , stereochemistry , electrochemistry , electrode , physics , quantum mechanics , thermodynamics

Polyynes spanning from a diyne to a dodecayne with adamantyl endgroups have been synthesized using the Fritsch–Buttenberg–Wiechell rearrangement as a key step to construct the acetylenic framework. Molecular properties as a function of polyyne length have been analyzed by UV–Vis spectroscopy, cyclic voltammetry, differential scanning calorimetry, and X‐ray crystallography. Copyright © 2011 John Wiley & Sons, Ltd.

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