Experimental consideration of covalent‐bonding interactions in stacks of singlet biradicals having Kekulé structures | Zendy

Shimizu Akihiro | Zendy; Nakano Masayoshi | Zendy; Hirao Yasukazu | Zendy; Kubo Takashi | Zendy

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Experimental consideration of covalent‐bonding interactions in stacks of singlet biradicals having Kekulé structures

Author(s) -

Shimizu Akihiro,

Nakano Masayoshi,

Hirao Yasukazu,

Kubo Takashi

Publication year - 2011

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1873

Subject(s) - chemistry , covalent bond , singlet state , stack (abstract data type) , molecule , solid state , chemical physics , computational chemistry , atomic physics , organic chemistry , excited state , physics , computer science , programming language

Kekulé singlet biradicals stabilized by phenalenyl rings afford one‐dimensional stacks in the solid state, in which covalent‐bonding interactions exist not only within a molecule but also between molecules. Through the covalent‐bonding interactions spreading over the stack, the lowest‐energy absorption band shifts to a lower‐energy region in the solid state relative to the solution band, and an electro‐conductive property in a single component state is also observed. Copyright © 2011 John Wiley & Sons, Ltd.

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