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Synthesis, structural, electrochemical, and photophysical properties of 4,2′‐thiopyrylogens – a novel class of sensitizers for photoinduced electron transfer reactions
Author(s) -
Warrier Ajaya Kumar Sankara,
Clennan Edward L.
Publication year - 2011
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.1697
Subject(s) - chemistry , electrochemistry , ring (chemistry) , electron transfer , oxygen atom , photochemistry , photoinduced electron transfer , sulfur , oxygen , combinatorial chemistry , computational chemistry , molecule , organic chemistry , electrode
The first three examples of the thioanalog of the 4,2′‐pyrylogen ring system are reported. The influence of the sulfur atom on the structural, electrochemical, and photophysical behavior of this ring system is discussed. In addition, these 4,2′‐thiopyrylogens are compared to their previously reported 4,4′‐isomers and their 4,4′‐ and 4,2′‐oxygen analogs. Copyright © 2010 John Wiley & Sons, Ltd.