Electrogenerated chemiluminescence of benzo 15‐crown‐5 derivatives | Zendy

Jiang Xiao | Zendy; Yang Xichuan | Zendy; Zhao Changzhi | Zendy; Sun Licheng | Zendy

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Electrogenerated chemiluminescence of benzo 15‐crown‐5 derivatives

Author(s) -

Jiang Xiao,

Yang Xichuan,

Zhao Changzhi,

Sun Licheng

Publication year - 2009

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1414

Subject(s) - chemistry , chemiluminescence , electrochemiluminescence , quantum yield , photochemistry , moiety , fluorescence , reagent , electrochemistry , dioxetane , monomer , solvent , organic chemistry , electrode , physics , quantum mechanics , polymer

Novel electrogenerated chemiluminescence (ECL) reagents C1 , C2 , and C3 with high fluorescence quantum yields bearing 15‐crown‐5 moiety have been synthesized and characterized. The photophysical, electrochemical, and ECL characters of these compounds have been studied in a 1:1 (v/v) PhH/MeCN mixed solvent. The ECL intensity is enhanced distinctly with the increase in the fluorescence quantum yield. Their ECL behaviors have been studied using annihilation and co‐reactant methods (tri‐ n ‐propylamine (TPrA) was used as a co‐reactant), respectively. The stable ECL emissions of compounds C1 – C3 can be ascribed to the typical and simple monomer ECL emission via S‐route. Copyright © 2008 John Wiley & Sons, Ltd.

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