Electrochemical glycosylation in the presence of a catalytic chemical mediator | Zendy

Drouin Ludovic | Zendy; Compton Richard G. | Zendy; Fairbanks Antony J. | Zendy

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Electrochemical glycosylation in the presence of a catalytic chemical mediator

Author(s) -

Drouin Ludovic,

Compton Richard G.,

Fairbanks Antony J.

Publication year - 2008

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1388

Subject(s) - chemistry , glycosylation , electrochemistry , mediator , catalysis , combinatorial chemistry , organic chemistry , biochemistry , electrode , microbiology and biotechnology , biology

Electrochemical glycosylation of thioglycoside donors proceeds efficiently in an undivided cell in the presence of a catalytic amount of the chemical mediator (4‐bromophenyl) ammoniumyl hexachloroantimonate (BAHA). In comparison with electrochemical glycosylation alone, the use of a catalytic amount of BAHA greatly increases the rate of reaction, reduces the potential required and inhibits ester‐protecting group migrations. Copyright © 2008 John Wiley & Sons, Ltd.

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