Kinetic study of electrochemically induced Michael reactions of  o ‐benzoquinones with 2‐acetylcyclohexanone and 2‐acetylcyclopentanone | Zendy

Nematollahi Davood | Zendy; Alimoradi Mohammad | Zendy; Rafiee Mohammad | Zendy

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Kinetic study of electrochemically induced Michael reactions of o ‐benzoquinones with 2‐acetylcyclohexanone and 2‐acetylcyclopentanone

Author(s) -

Nematollahi Davood,

Alimoradi Mohammad,

Rafiee Mohammad

Publication year - 2007

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1125

Subject(s) - chemistry , kinetic energy , michael reaction , computational chemistry , organic chemistry , catalysis , classical mechanics , physics

The reaction of electrochemically generated o ‐benzoquinones ( 2a‐f ) as Michael acceptors with 2‐acetylcyclohexanone (ACH) and 2‐acetylcyclopentanone (ACP), as nucleophiles has been studied in various pHs using cyclic voltammetry. The results indicate that the participation of o ‐benzoquinones ( 2a‐f ) in the Michael reaction with acetylcyclohexanone (ACH) to form the corresponding catechol derivatives ( 4a‐f ). Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. Copyright © 2007 John Wiley & Sons, Ltd.

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