Degenerate thermal isomerizations of  Z ‐ethylidene‐2‐methylcyclobutane | Zendy

Baldwin John E. | Zendy

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Degenerate thermal isomerizations of Z ‐ethylidene‐2‐methylcyclobutane

Author(s) -

Baldwin John E.

Publication year - 2006

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.1043

Subject(s) - chemistry , degenerate energy levels , sigmatropic reaction , thermal , deuterium , computational chemistry , isomerization , organic chemistry , nuclear physics , thermodynamics , catalysis , physics , quantum mechanics

The stereochemical and mechanistic aspects of the degenerate thermal isomerizations available to deuterium‐labeled Z ‐ethylidene‐2‐methylcyclobutanes remain incompletely defined. Relevant data and several conjectural readings of the data are reconsidered in light of current understandings of thermal stereomutations and [1,3] carbon sigmatropic shifts. Copyright © 2006 John Wiley & Sons, Ltd.

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