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Optically induced electron transfer in an N , N , N ′, N ′‐tetraanisyl‐ o ‐phenylenediamine radical cation
Author(s) -
Nöll Gilbert,
Avola Manuele
Publication year - 2006
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.1024
Subject(s) - chemistry , delocalized electron , radical ion , electrochemistry , electron transfer , photochemistry , electron , medicinal chemistry , ion , organic chemistry , electrode , quantum mechanics , physics
Upon electrochemical and spectroelectrochemical investigation the radical cation of tetraanisyl‐ o ‐phenylenediamine turned out to be an almost delocalized system at the borderline between class II and III with an extremely low reorganization energy. Copyright © 2006 John Wiley & Sons, Ltd.
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