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Discriminating bulk versus interface shunts in organic solar cells by advanced imaging techniques
Author(s) -
Karl André,
Osvet Andres,
Vetter Andreas,
Maisch Philipp,
Li Ning,
Egelhaaf HansJoachim,
Brabec Christoph J.
Publication year - 2019
Publication title -
progress in photovoltaics: research and applications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.286
H-Index - 131
eISSN - 1099-159X
pISSN - 1062-7995
DOI - 10.1002/pip.3121
Subject(s) - thermography , materials science , optoelectronics , electroluminescence , stack (abstract data type) , heterojunction , interface (matter) , laser , femtosecond , photovoltaics , organic solar cell , photoluminescence , active layer , photovoltaic system , layer (electronics) , optics , nanotechnology , computer science , infrared , polymer , electrical engineering , physics , engineering , thin film transistor , capillary number , capillary action , composite material , programming language
An important aspect when upscaling organic photovoltaics from laboratory to industrial scale is quality control. Established imaging techniques like lock‐in thermography or luminescence imaging are frequently used for this purpose. While these techniques allow for the lateral detection of defects, they cannot provide information on the vertical position of the defect in the OPV stack. Here, we present an approach to overcome this limitation. A femtosecond‐laser is deployed to introduce well‐defined artificial calibration defects selectively into both the interface and the bulk active layer of inverted P3HT:PCBM bulk heterojunction cells during device fabrication. The defective cells are then characterized using J‐V analysis and several nondestructive imaging methods (dark lock‐in thermography, photoluminescence, and electroluminescence imaging). The distinct response for each defect in the different imaging methods enables us to uniquely distinguish between bulk and interface defects. This allows to study surface recombination under most controlled conditions.