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Bending behaviour of electroresponsive poly(vinyl alcohol)/poly(acrylic acid) semi‐interpenetrating network hydrogel fibres under an electric stimulus
Author(s) -
Fei Jiainqi,
Zhang Zipeng,
Gu Lixia
Publication year - 2002
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.910
Subject(s) - vinyl alcohol , materials science , composite material , acrylic acid , interpenetrating polymer network , spinning , ionic bonding , swelling , electric field , glutaraldehyde , ultimate tensile strength , bending , polymer chemistry , polymer , chemistry , ion , physics , monomer , organic chemistry , quantum mechanics , chromatography
Poly(vinyl alcohol) (PVA) and poly(acrylic acid) (PAA) composite fibres were prepared via solution spinning and subsequently, semi‐interpenetrating networks (SIPN) were obtained by crosslinking the fibres with glutaraldehyde. The hydrogel fibres exhibited bending behaviour under DC electric stimulation. The effects of a number of factors have been systematically studied, including the PAA content within the network, electric voltage imposed across the fibre, the fibre diameter, concentration of the crosslinking agent, pH and ionic strength of the bath solution. Our experimental results show a stable reversibility of bending behaviour under the applied electric field. The degree of bending at equilibrium and the bending speed of the hydrogel fibre increased with the intensity of the applied electric voltage and the PAA content having negatively charged ionic groups within the SIPN. The electroresponsive behaviour of the present SIPN hydrogel fibre was also affected by the aforementioned extrinsic factors. These observations are interpreted in terms of fibre stiffness, fixed charge density and swelling pressure, which depend on the hydrogel equilibrium states in different pH and ionic environments together with the electrochemical reactions under DC electric field. © 2002 Society of Chemical Industry