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Effect of styrene addition on chemically induced grafting of 4‐vinylbenzyl chloride onto low‐density polyethylene for anion exchange membrane preparation
Author(s) -
Chen Zhichao,
Huang Di,
Hwang JiannYang
Publication year - 2019
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.5788
Subject(s) - polymerization , styrene , polymer chemistry , polyethylene , membrane , chemistry , ion exchange , polyvinyl chloride , grafting , chloride , amination , titration , organic chemistry , polymer , copolymer , ion , catalysis , biochemistry
Anion exchange membranes were prepared from graft polymerization of 4‐vinylbenzyl chloride on low‐density polyethylene matrix and subsequent amination with trimethylamine solution. The graft polymerization was initiated by benzoyl peroxide instead of gamma ray radiation. The resulting membranes had insufficient anion exchange functional groups; however, this could be enhanced by adding 10% styrene to 4‐vinylbenzyl chloride in a graft polymerization reaction. Further addition of styrene resulted in a decrease of the ion exchange capacity of anion exchange membranes due to competition with 4‐vinylbenzyl chloride in graft polymerization onto polyethylene. These were evidenced by analytical titration, elemental analysis, infrared spectroscopy and 1 H NMR. © 2019 Society of Chemical Industry