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Study of the partial wetting morphology in polylactide/poly[(butylene adipate)‐ co ‐terephthalate]/polyamide ternary blends: case of composite droplets
Author(s) -
Fu Yang,
Fodorean Gabriel,
Navard Patrick,
PeuvrelDisdier Edith
Publication year - 2018
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.5651
Subject(s) - ternary operation , adipate , materials science , wetting , polyamide , morphology (biology) , surface tension , polymer , composite number , chemical engineering , viscosity , composite material , polymer blend , extrusion , surface energy , polymer chemistry , thermodynamics , copolymer , physics , biology , computer science , engineering , genetics , programming language
Abstract The prediction of the morphology of ternary polymer blends requires a good knowledge of the values of the three interfacial tensions. We selected three polymers, either biobased or biodegradable, polyamide (PA), poly[(butylene adipate)‐ co ‐terephthalate] (PBAT) and polylactide (PLA), and we accurately measured their interfacial tensions using the retraction method, varying the molar mass or inverting the phases. The following values of interfacial tension were obtained: γ PBAT/PLA = 3.3 ± 0.7 mN m −1 , γ PA/PLA = 5.6 ± 0.3 mN m −1 and γ PBAT/PA = 3.0 ± 0.4 mN m −1 . These values were used to calculate the spreading coefficients giving rise to two negative coefficients and one coefficient close to zero. Ternary blends with various compositions, two different levels of viscosity for PBAT and different processing conditions were prepared. There was a very good agreement between the predictions of the spreading theory, when using the values of interfacial tension of the right order of magnitude, and the observed morphologies, whatever the polymer serving as a matrix. When PLA or PBAT was chosen as the matrix, the ternary blend morphology was composed of composite droplets, presenting a partial wetting morphology, dispersed in the polymer matrix. This morphology was observed whatever the composition, the viscosity of the PBAT phase and the processing conditions. A further calculation of the free energy confirmed this morphology. The formation process of this semi‐encapsulated morphology was observed during blending. © 2018 Society of Chemical Industry