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Electropolymerization of hydrogen bond supramolecular associations between terthiophene‐3‐acetic acid and 4,4′‐bipyridine
Author(s) -
Beouch Layla,
Boileau Sylvie,
Chevrot Claude,
TranVan François
Publication year - 2017
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.5389
Subject(s) - hydrogen bond , supramolecular chemistry , terthiophene , acetonitrile , acetic acid , supramolecular polymers , fourier transform infrared spectroscopy , polymer chemistry , methylene , polymer , materials science , chemistry , organic chemistry , molecule , chemical engineering , engineering
Supramolecular assemblies based on 4,4′‐bipyridine as hydrogen acceptor and a terthiophene carboxylic acid (3‐ TTAA ) as hydrogen donor were synthesized and characterized by Fourier transform IR spectroscopy and DSC . Their electropolymerization was successful in methylene chloride or acetonitrile. The concept of using such supramolecular assemblies in electropolymerization opens the way to the facile synthesis of new π‐conjugated polymers. © 2017 Society of Chemical Industry