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Effect of lactic acid chain length on thermomechanical properties of star ‐ LA ‐xylitol resins and jute reinforced biocomposites
Author(s) -
Jahandideh Arash,
Esmaeili Nima,
Muthukumarappan Kasiviswanathan
Publication year - 2017
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.5354
Subject(s) - materials science , composite material , glass transition , dynamic mechanical analysis , rheometry , biocomposite , flexural strength , ultimate tensile strength , fourier transform infrared spectroscopy , heat deflection temperature , izod impact strength test , composite number , polymer , chemical engineering , engineering
Star‐shaped bio‐based resins were synthesized by direct condensation of lactic acid ( LA ) with xylitol followed by end‐functionalizing of branches by methacrylic anhydride with three different LA chain lengths (3, 5 and 7). The thermomechanical and structural properties of the resins were characterized by 13 C NMR , Fourier transform IR spectroscopy, rheometry, DSC , dynamic mechanical analysis ( DMA ), TGA and flexural and tensile tests. An evaluation of the effect of chain length on the synthesized resins showed that the resin with five LAs exhibited the most favorable thermomechanical properties. Also, the resin's glass transition temperature (103 °C) was substantially higher than that of the thermoplast PLA ( ca 55 °C). The resin had low viscosity at its processing temperature (80 °C). The compatibility of the resin with natural fibers was investigated for biocomposite manufacturing. Finally, composites were produced from the n5‐resin (80 wt% fiber content) using jute fiber. The thermomechanical and morphological properties of the biocomposites were compared with jute‐ PLA composites and a hybrid composite made of the impregnated jute fibers with n5 resin and PLA . SEM and DMA showed that the n5‐jute composites had better mechanical properties than the other composites produced. Inexpensive monomers, good thermomechanical properties and good processability of the n5 resin make the resin comparable with commercial unsaturated polyester resins. © 2017 Society of Chemical Industry