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Super‐toughened poly( l ‐lactic acid) fabricated via reactive blending and interfacial compatibilization
Author(s) -
Ma Meng,
Zheng Haiming,
Chen Si,
Wu Bozhen,
He Huiwen,
Chen Liqing,
Wang Xu
Publication year - 2016
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.5174
Subject(s) - materials science , compatibilization , toughness , composite material , polyurethane , dynamic mechanical analysis , elongation , izod impact strength test , rheology , polymer , polymer blend , ultimate tensile strength , copolymer
Abstract Super‐toughened poly( l ‐lactic acid) ( PLLA ) was prepared by reactive blending of PLLA with poly(ϵ‐caprolactone) ( PCL ), glycerol and 4,4′‐methylenediphenyl diisocyanate. The reactive interfacial compatibility between PLLA and the formed crosslinked polyurethane ( CPU ) in the PLLA matrix was studied in detail. The morphology and the toughness of the blends can be tuned by changing the CPU content. The results indicate that the impact strength of PLLA shows a tendency to higher values with the increasing PCL content up to 20 wt%. The notched impact strength of the blend with 20 wt% PCL increases to 55.01 kJ m −2 , which is 24.9 times higher than that of neat PLLA . The elongation at break is also increased from 5% to 139.4%, indicating the brittle − ductile transition. The increased interfacial binding strength through the reactive interfacial compatibility and the formation of a CPU network in the PLLA matrix account for the improved toughness of PLLA / CPU blends. Dynamic mechanical analysis results indicate that the compatibility between PLLA and CPU is improved with increasing CPU content resulting in the formation of more interfacial phase. In addition, rheological property measurements indicate that the improvement in storage modulus and complex viscosity is ascribed to the formation of a CPU network in the PLLA matrix. © 2016 Society of Chemical Industry