Curing theory of the A ai –B bj  type polycondensation. (I) intramolecular cyclization and gelation equations | Zendy

Zheng FuAn | Zendy; Liu FengQi | Zendy; Tang XinYi | Zendy

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Curing theory of the A ai –B bj type polycondensation. (I) intramolecular cyclization and gelation equations

Author(s) -

Zheng FuAn,

Liu FengQi,

Tang XinYi

Publication year - 1993

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.4990310407

Subject(s) - intramolecular force , intermolecular force , condensation polymer , intramolecular reaction , branching (polymer chemistry) , curing (chemistry) , polymer chemistry , materials science , chemistry , polymer science , polymer , stereochemistry , molecule , organic chemistry

This paper investigates in detail the ring‐chain competition in A ai –B bj type polycondensations by use of a molecular model of tree branching and the basic principles of probability. The intramolecular cyclization equations and the critical gelation condition containing both intermolecular and intramolecular reaction parameters have been obtained.

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