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Effect of confinement on glass dynamics and free volume in immiscible polystyrene/high‐density polyethylene blends
Author(s) -
Wu Lingyun,
Zhu Jingjun,
Liao Xia,
Ni Kai,
Zhang Qiongwen,
An Zhu,
Yang Qi,
Li Guangxian
Publication year - 2015
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4862
Subject(s) - high density polyethylene , materials science , polystyrene , polyethylene , glass transition , amorphous solid , composite material , crystallization , annealing (glass) , volume (thermodynamics) , phase (matter) , polymer chemistry , chemical engineering , polymer , thermodynamics , chemistry , crystallography , organic chemistry , physics , engineering
The free volume radius of PS / HDPE blend decreased upon annealing, which verified the confinement effect of constriction during crystallization process in the incompatible amorphous/semi‐crystalline blend.