New types of associating monomers and polymers from  α ‐aminocaprolactam and 2‐isocyanatoethyl (meth)acrylate: properties in condensed phase and in solution | Zendy

Mondrzyk Adam | Zendy; Ritter Helmut | Zendy

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New types of associating monomers and polymers from α ‐aminocaprolactam and 2‐isocyanatoethyl (meth)acrylate: properties in condensed phase and in solution

Author(s) -

Mondrzyk Adam,

Ritter Helmut

Publication year - 2015

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.4813

Subject(s) - copolymer , monomer , acrylate , isocyanate , polymer chemistry , materials science , ethyl acrylate , polymer , lower critical solution temperature , meth , hydrogen bond , chemical engineering , chemistry , organic chemistry , molecule , polyurethane , composite material , engineering

New highly crystalline ureido‐containing monomers were simply prepared from α ‐aminocaprolactam and 2‐isocyanatoethyl (meth)acrylate and polymerized radically. The resulting homopolymers are semi‐crystalline and strongly aggregate, showing upper critical solution temperature behaviour in ethanol–water. Radically synthesized copolymers with hydrophilic N , N ‐dimethylacrylamide show lower critical solution temperature behaviour in water. At a certain molecular weight, physical networks of copolymer are formed in water.

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