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Synthesis of chitosan‐ graft ‐poly[2‐cyano‐1‐(pyridin‐3‐yl)allyl acrylate] copolymer from a novel monomer, prepared using a Morita–Baylis–Hillman reaction, and characterization of its antimicrobial activity
Author(s) -
Khalil Khaled D,
Ibrahim Enas I,
AlSagheer Fakhreia A
Publication year - 2014
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4760
Subject(s) - monomer , acrylonitrile , polymer chemistry , methyl acrylate , chitosan , grafting , acryloyl chloride , copolymer , acrylate , chemistry , nuclear chemistry , materials science , polymer , organic chemistry
Synthesis of chitosan‐ graft ‐poly[2‐cyano‐1‐(pyridin‐3‐yl)allyl acrylate] copolymer from a novel monomer, prepared using a Morita–Baylis–Hillman reaction, and characterization of its antimicrobial activity A novel way is described to modify the natural polymer chitosan via a Morita–Baylis–Hillman ( MBH ) reaction. The MBH acrylate monomer was synthesized and then grafted onto chitosan using a persulfate–sulfite redox system.