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Trimethylsilyl‐substituted triazole‐based ligand for copper‐mediated single‐electron transfer living radical polymerization of methyl methacrylate
Author(s) -
Sangtrirutnugul Preeyanuch,
Wised Kritdikul,
Maisopa Purmpoon,
Trongsiriwat Nisalak,
Tangboriboonrat Pramuan,
Reutrakul Vichai
Publication year - 2014
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4719
Subject(s) - chemistry , polymerization , polymer chemistry , methyl methacrylate , dispersity , copper , trimethylsilyl , radical polymerization , ligand (biochemistry) , amine gas treating , polymer , photochemistry , organic chemistry , biochemistry , receptor
The tripodal ‘click’ ligand tris(4‐trimethylsilyl‐1,2,3‐triazolylmethyl)amine ( TTTA ) is effective at promoting copper‐catalysed single‐electron transfer living radical polymerization of methyl methacrylate in bulk. The corresponding copper species allow well‐controlled polymerizations under aerobic conditions.