Controlled synthesis of poly[(butyl methacrylate)‐ co ‐(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement | Zendy

Payne Kevin A | Zendy; Van Steenberge Paul HM | Zendy; D'hooge Dagmar R | Zendy; Reyniers MarieFrançoise | Zendy; Marin Guy B | Zendy; Hutchinson Robin A | Zendy; Cunningham Michael F | Zendy

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Controlled synthesis of poly[(butyl methacrylate)‐ co ‐(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement

Author(s) -

Payne Kevin A,

Van Steenberge Paul HM,

D'hooge Dagmar R,

Reyniers MarieFrançoise,

Marin Guy B,

Hutchinson Robin A,

Cunningham Michael F

Publication year - 2014

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.4678

Subject(s) - polymer chemistry , polymerization , catalytic chain transfer , chain transfer , radical polymerization , atom transfer radical polymerization , materials science , butyl acrylate , bulk polymerization , dispersity , acrylate , copolymer , living free radical polymerization , monomer , chemistry , photochemistry , methyl methacrylate , polymer , organic chemistry

Copolymerization by ARGET ATRP is investigated to improve polymerization rate and initiator efficiency. Semi‐batch addition of reducing agent (Sn( EH ) 2 ) is shown to significantly increase the polymerization rate.

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