Enzymatically synthesized polyesters with pendent  OH  groups as macroinitiators for the preparation of well‐defined graft copolymers by atom transfer radical polymerization | Zendy

Jbeily Mark | Zendy; Naolou Toufik | Zendy; Bilal Muhammad | Zendy; Amado Elkin | Zendy; Kressler Jörg | Zendy

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Enzymatically synthesized polyesters with pendent OH groups as macroinitiators for the preparation of well‐defined graft copolymers by atom transfer radical polymerization

Author(s) -

Jbeily Mark,

Naolou Toufik,

Bilal Muhammad,

Amado Elkin,

Kressler Jörg

Publication year - 2014

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.4676

Subject(s) - atom transfer radical polymerization , adipate , polymer chemistry , polyester , copolymer , polymerization , condensation polymer , caprolactone , materials science , chemistry , organic chemistry , catalysis , polymer

A family of polyesters, poly(glycerol adipate) ( PGA ), poly(sorbitol adipate) and PGA ‐ graft ‐poly( ε ‐caprolactone), synthesized by enzymatic polycondensation were converted into atom transfer radical polymerization macroinitiators. Glycerol monomethacrylate ( GMA ) was polymerized from a PGA backbone yielding the amphiphilic PGA ‐ graft ‐ PGMA .

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