Premium
Thiol‐Michael coupling and ring‐opening metathesis polymerization: facile access to functional exo ‐7‐oxanorbornene dendron macromonomers
Author(s) -
Liu Meina,
Burford Robert P.,
Lowe Andrew B.
Publication year - 2014
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4664
Subject(s) - romp , metathesis , polymerization , thioether , monomer , polymer chemistry , dendrimer , nucleophile , ring opening metathesis polymerisation , chemistry , alkoxy group , functional polymers , polymer , organic chemistry , catalysis , alkyl
Thiol‐Michael Coupling and ROMP : Facile Access to Functional exo ‐7‐Oxanorbornene Dendron Macromonomers Nucleophile‐mediated thiol‐Michael coupling is employed to prepare a small library of functional thioether‐based dendron monomers from novel di‐ and tetra‐acrylate functional ring‐opening metathesis polymerization ( ROMP )‐active exo ‐7‐oxanorbornene‐based monomers. The ROMP (co)polymerization of these novel monomers is evaluated with Grubbs 1 st and 3 rd generation initators.