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A new post‐metallocene catalyst for alkene polymerization: copolymerization of ethylene and 1‐hexene with titanium complexes bearing N,N ‐dialkylcarbamato ligands
Author(s) -
Hayatifar Mohammad,
Pampaloni Guido,
Bernazzani Luca,
Capacchione Carmine,
Kissin Yury V.,
Raspolli Galletti Anna Maria
Publication year - 2014
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4558
Subject(s) - metallocene , 1 hexene , hexene , ethylene , chlorobenzene , polymer chemistry , polymerization , catalysis , copolymer , methylaluminoxane , titanium , alkene , materials science , molar mass distribution , solvent , organic chemistry , chemistry , polymer
New catatytic systems based on N,N ‐dialkylcarbamato Ti( IV ) precursors for copolymerization of ethylene and 1‐hexene are presented. High 1‐hexene content in the copolymers and a multi‐site nature of the catalytic systems were ascertained.