A new post‐metallocene catalyst for alkene polymerization: copolymerization of ethylene and 1‐hexene with titanium complexes bearing  N,N ‐dialkylcarbamato ligands | Zendy

Hayatifar Mohammad | Zendy; Pampaloni Guido | Zendy; Bernazzani Luca | Zendy; Capacchione Carmine | Zendy; Kissin Yury V. | Zendy; Raspolli Galletti Anna Maria | Zendy

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A new post‐metallocene catalyst for alkene polymerization: copolymerization of ethylene and 1‐hexene with titanium complexes bearing N,N ‐dialkylcarbamato ligands

Author(s) -

Hayatifar Mohammad,

Pampaloni Guido,

Bernazzani Luca,

Capacchione Carmine,

Kissin Yury V.,

Raspolli Galletti Anna Maria

Publication year - 2014

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.4558

Subject(s) - metallocene , 1 hexene , hexene , ethylene , chlorobenzene , polymer chemistry , polymerization , catalysis , copolymer , methylaluminoxane , titanium , alkene , materials science , molar mass distribution , solvent , organic chemistry , chemistry , polymer

New catatytic systems based on N,N ‐dialkylcarbamato Ti( IV ) precursors for copolymerization of ethylene and 1‐hexene are presented. High 1‐hexene content in the copolymers and a multi‐site nature of the catalytic systems were ascertained.

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