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Polymer particle adsorption at textile/liquid interfaces: a simple approach for a new functionalization route
Author(s) -
Ripoll Lionel,
Bordes Claire,
Marote Pedro,
Etheve Sabrina,
Elaissari Abdelhamid,
Fessi Hatem
Publication year - 2012
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.4190
Subject(s) - adsorption , chemical engineering , materials science , surface modification , particle (ecology) , polymer , emulsion polymerization , cationic polymerization , polyamide , ionic strength , textile , polymer chemistry , emulsion , particle size , colloid , polymerization , langmuir adsorption model , composite material , chemistry , organic chemistry , aqueous solution , oceanography , engineering , geology
Abstract The adsorption of amino‐functionalized poly(methyl methacrylate) particles prepared by emulsion polymerization onto polyamide/elastane fibres was investigated. The influence of several physicochemical parameters (pH, ionic strength) on the colloidal stability and surface properties of the cationic latex particles was first examined. Then, particle adsorption was studied as a function of particle concentration, particle size, time, pH and salinity. The results obtained demonstrated that the adsorption process was mainly governed by electrostatic interactions and the adsorption isotherms were analysed on the basis of a Langmuir model. Finally, the effect of washing steps on the adsorbed particles was investigated. The results obtained indicated strong interactions between particles and textile fibres. Copyright © 2012 Society of Chemical Industry