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Surface modification using bio‐inspired adhesive polymers based on polyaspartamide derivatives
Author(s) -
An Jung Hyun,
Huynh Ngoc Thach,
Sil Jeon Young,
Kim JiHeung
Publication year - 2011
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.3116
Subject(s) - adhesive , materials science , catechol , aminolysis , contact angle , surface modification , wetting , polymer , coating , chemical engineering , aqueous solution , x ray photoelectron spectroscopy , bioadhesive , adhesion , ethylenediamine , polymer chemistry , composite material , organic chemistry , chemistry , catalysis , layer (electronics) , engineering
The catechol functional group of dopamine (3,4‐dihydroxyphenethylamine) has the ability to form strong adhesive bonds to inorganic and organic surfaces in aqueous environments. In this study, novel adhesive polyaspartamides containing catechol pendant groups were synthesized from polysuccinimide through successive aminolysis reactions with quantitative dopamine and ethylenediamine. The adhesion and crosslinking of dopamine‐modified polyaspartamide in aqueous alkaline media was used successfully to modify the surface of various materials (including synthetic polymers, metals, metal oxides, ceramics) using a simple immersion method. Contact angle measurements, SEM and X‐ray photoelectron spectroscopy of the modified surfaces were used to verify the surface coating on a variety of materials with very different inherent wetting properties. These novel biocompatible polymers have potential industrial and biomedical applications as adhesives or coating materials for functional surface modification. Copyright © 2011 Society of Chemical Industry