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Efficient dispersion of multi‐walled carbon nanotubes by in situ polymerization
Author(s) -
Hu Nantao,
Zhou Hongwei,
Dang Guodong,
Rao Xianhua,
Chen Chunhai,
Zhang Wanjin
Publication year - 2007
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.2187
Subject(s) - carbon nanotube , materials science , nanocomposite , polyimide , in situ polymerization , monomer , polymerization , polymer , dispersion (optics) , composite material , dispersion polymerization , polymer chemistry , chemical engineering , layer (electronics) , physics , optics , engineering
Multi‐walled carbon nanotube (MWNT)‐reinforced polyimide nanocomposites were synthesized by in situ polymerization of monomers in the presence of acylated MWNTs. The acyl groups associated with the MWNTs participated in the reaction through the formation of amide bonds. This process enabled uniform dispersion of MWNT bundles in the polymer matrix. The resultant MWNT–polyimide nanocomposite films were optically transparent with significant mechanical enhancement at a very low loading (0.5 wt%). Evidence has been obtained for improved interactions between the nanotubes and the matrix polymer. Copyright © 2006 Society of Chemical Industry