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Photopolymerization of carbazolyloxiranes
Author(s) -
Gražulevičius Juozas V.,
Kavaliūnas Rimtautus,
Lazauskaitė Rūta
Publication year - 1995
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1995.210360111
Subject(s) - photoinitiator , photopolymer , polymerization , monomer , polymer chemistry , materials science , ether , degree of polymerization , chemistry , organic chemistry , polymer , composite material
Photopolymerizations of 1‐allyloxy‐3‐(carbazol‐9‐yl)‐2‐propanol glycidyl ether and 1‐(carbazol‐9‐yl)‐4‐oxa‐2‐pentanol glycidyl ether with diaryliodonium salts in solution and in bulk are reported. These reactions give oligomers of degree of polymerization 4–6. The influence of the functional groups of the monomers on the rate of polymerization, conversion limit and molecular weight is discussed. The effects of photoinitiator and reaction media on these factors have also been studied.