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Metal chelates with some cellulose derivatives. Part I. Preparation and characterization of chromium (III)–carboxymethyl cellulose complexes
Author(s) -
ElSaied Houssni,
Basta Altaf H.,
AbdelHadi Afkar K.,
Hosny Wafaa M.
Publication year - 1994
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1994.210350102
Subject(s) - carboxymethyl cellulose , chelation , chemistry , chromium , aqueous solution , inorganic chemistry , metal ions in aqueous solution , polymer chemistry , metal , ligand (biochemistry) , cellulose , ether , nuclear chemistry , sodium , organic chemistry , biochemistry , receptor
A systematic spectrophotometric study on the complexation of chromium (III) ion with sodium carboxymethyl cellulose (CMC) was carried out. The effects of the degree of substitution (DS) of the polymer, the concentrations of Cr(III) and CMC solutions, the pH and temperature on the complex formation were studied in the aqueous state. CMC complexes with Cr(III) were characterized by elemental analysis, magnetic moment and spectral (Vis and IR) data. The results showed that CMC (L) chelated to the metal ion according to the formula CrL 2 · 2H 2 O. The ligand field parameters, namely D q , B and β were calculated; the β‐values indicate strong covalency in the ligand σ bond. The IR spectra revealed that the chelating sites of CMC are not only the carboxymethyl groups, via the ether‐ and the carboxyl‐oxygen atoms, but also the secondary hydroxyl groups.