Photopolymerization of acrylate derivatives initiated by hexaarylbiimidazole with ether groups | Zendy

Shi Yongtao | Zendy; Yin Jie | Zendy; Kaji Makoto | Zendy; Yori Hanako | Zendy

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Photopolymerization of acrylate derivatives initiated by hexaarylbiimidazole with ether groups

Author(s) -

Shi Yongtao,

Yin Jie,

Kaji Makoto,

Yori Hanako

Publication year - 2006

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1968

Subject(s) - photopolymer , benzil , acrylate , ethylene glycol , photochemistry , ether , acrylate polymer , propane , photoinitiator , benzophenone , polymer chemistry , fluorescence , chemistry , materials science , polymer , organic chemistry , polymerization , monomer , physics , quantum mechanics , catalysis

A novel hexaarylbiimidazole derivative 2,2′‐bis‐(2‐chlorophenyl)‐4,4′,5,5′‐tetra‐[3‐(2‐hydroxyl‐3‐ethylene glycol monoethylene ether‐propane‐1‐oxy)‐phenyl]‐1,2′‐biimidazole (BCTE‐HABI) was synthesized from 3,3′‐dihydroxyl benzil. Ultraviolet spectra, fluorescence spectra, ESR measurements, photo‐dilatometer experiments and photo‐DSC measurements indicated its good UV‐visible absorption ability, high photolysis efficiency and efficient photo‐initiation for acrylates. Copyright © 2006 Society of Chemical Industry

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