Synthesis of isoelectronic polyazomethine and poly(arylene vinylene) by a palladium‐catalyzed Suzuki coupling method | Zendy

Grigoras Mircea | Zendy; Antonoaia Nicoleta Cristina | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of isoelectronic polyazomethine and poly(arylene vinylene) by a palladium‐catalyzed Suzuki coupling method

Author(s) -

Grigoras Mircea,

Antonoaia Nicoleta Cristina

Publication year - 2005

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1895

Subject(s) - arylene , fluorene , carbazole , polymer chemistry , copolymer , suzuki reaction , materials science , condensation polymer , palladium , monomer , conjugated system , catalysis , photochemistry , chemistry , polymer , organic chemistry , aryl , alkyl , composite material

Two fully conjugated copolymers containing 2,7‐(9,9‐dioctyl) fluorene and 3,6‐( N ‐hexyl‐9 H ‐carbazole) disubstituted rings and arylene vinylene or azomethine units in the main chain were synthesized through a palladium‐catalyzed Suzuki coupling method of 2,7‐bis(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)‐9,9‐dioctyl fluorene with 1,4‐bis(6‐bromo‐ N ‐hexyl‐9 H ‐carbazole‐3‐yl vinyl) benzene or N , N ‐bis(6‐bromo‐ N ‐hexyl‐9 H ‐carbazole‐3‐yl methylidene) 1,4‐phenylenediamine. Bisbromine arylene vinylene and arylenazomethine monomers were synthesized by condensation of 3‐formyl‐ N ‐hexyl‐6‐bromo carbazole with tetraethyl‐ p ‐xylylene diphosphonate or 1,4‐phenylenediamine. Copolymers were characterized by FTIR, 1 H‐NMR, DSC, UV‐visible and photoluminescence methods. Copyright © 2005 Society of Chemical Industry

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research