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Fast crystallization of poly(3‐hydroxybutyrate) and poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyvalerate) with talc and boron nitride as nucleating agents
Author(s) -
Kai Weihua,
He Yong,
Inoue Yoshio
Publication year - 2005
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1758
Subject(s) - talc , crystallization , differential scanning calorimetry , nucleation , chemical engineering , materials science , boron nitride , polymer chemistry , crystallinity , gel permeation chromatography , organic chemistry , chemistry , composite material , polymer , physics , engineering , thermodynamics
The crystallization behavior of poly(3‐hydroxybutyrate) (PHB) and poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyvalerate) (PHBV) induced by two kinds of nucleating agents, boron nitride (BN) and talc, was investigated by differential scanning calorimetry, polarized optical microscopy and X‐ray diffraction. Both BN and talc have good nucleating ability in the crystallization of PHB and PHBV. From these results, combined with molecular weight measurement by gel permeation chromatography, the mechanism of nucleation by BN and talc in the crystallization of PHB and PHBV has been proposed. BN acts as a nucleating agent itself and initiates nucleation in the crystallization of PHB and PHBV. Talc acts in a different way. It reacts as a chemical reagent with the molten chains of PHB/PHBV, while the reaction product acts as the true nucleating agent, which lowers the crystallization barriers of PHB and PHBV. 1 H NMR spectroscopy provides evidence for the reaction between PHB and talc and supports the proposed nucleation mechanism. Copyright © 2005 Society of Chemical Industry