Synthesis and characterization of UV‐curable acrylic resin containing fluorine groups | Zendy

Park SooJin | Zendy; Jin FanLong | Zendy

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Synthesis and characterization of UV‐curable acrylic resin containing fluorine groups

Author(s) -

Park SooJin,

Jin FanLong

Publication year - 2005

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1755

Subject(s) - photoinitiator , thermal stability , materials science , glass transition , acrylic resin , fourier transform infrared spectroscopy , dielectric , fluorine , polymer chemistry , polarizability , composite material , chemical engineering , nuclear chemistry , organic chemistry , chemistry , polymer , coating , monomer , optoelectronics , molecule , engineering , metallurgy

A novel fluorine‐containing acrylic resin, 4‐trifluoromethylphenyl glycerol dimethacrylate (TPGD), was synthesized and the structure was characterized by FTIR, 13 C NMR, 1 H NMR, and 19 F NMR spectroscopy. The conversion of cure reaction, thermal stability, glass transition temperature ( T g ), and electrical properties of the TPGD acrylic resin cured with UV radiation were investigated. The thermal stability and T g of the UV‐cured specimens show a maximum value at 1 wt% photoinitiator, due to the formation of advanced network structures. The cured specimens had a relatively low dielectric constant, attributed to the decreased deformation polarizability of segment motion in the fluorine‐containing resin. Copyright © 2004 Society of Chemical Industry

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