Premium
Nanocomposites of polymer gel electrolyte based on poly(ethylene glycol diacrylate) and Mg–Al layered double hydroxides
Author(s) -
Cho Mi Suk,
Shin Bora,
Nam Jae Do,
Lee Youngkwan,
Song Kigook
Publication year - 2004
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1592
Subject(s) - layered double hydroxides , nanocomposite , materials science , ionic conductivity , hydroxide , ethylene glycol , electrolyte , polymer , chemical engineering , ultimate tensile strength , conductivity , polymer nanocomposite , composite number , ionic strength , polymer chemistry , composite material , chemistry , organic chemistry , electrode , aqueous solution , engineering
Abstract The present paper describes the synthesis and characterization of nanocomposite materials composed of the polymer gel electrolyte and a layered double hydroxide (LDH) inorganic filler. Mg–Al LDHs were prepared with various ratios of Mg/Al. It was observed that the layered structure of Mg–Al LDH was totally exfoliated by the PEGDA. The ionic conductivity and mechanical strength were highly improved in the nanocomposite systems. In the case of the composite films having 4.5 wt% of the Mg–Al LDH, the ionic conductivity reached 1.6 × 10 −3 S cm −1 at room temperature. The incorporation of nanoparticles into the gel resulted in a two‐ or threefold increase in the tensile modulus. Copyright © 2004 Society of Chemical Industry