Rapid living free‐radical polymerization of methyl acrylate under  60 Co γ‐ray irradiation at room temperature | Zendy

Hua Daoben | Zendy; Cheng Kun | Zendy; Bai Ruke | Zendy; Lu Weiqi | Zendy; Pan Caiyuan | Zendy

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Rapid living free‐radical polymerization of methyl acrylate under 60 Co γ‐ray irradiation at room temperature

Author(s) -

Hua Daoben,

Cheng Kun,

Bai Ruke,

Lu Weiqi,

Pan Caiyuan

Publication year - 2004

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1525

Subject(s) - polymerization , methyl acrylate , irradiation , living free radical polymerization , polymer chemistry , radical polymerization , acrylate , polymer , materials science , living polymerization , photochemistry , chemistry , copolymer , organic chemistry , physics , nuclear physics

Rapid living free‐radical polymerization of methyl acrylate under 60 Co γ‐ray irradiation in the presence of benzyl 1 H ‐imidazole‐1‐carbodithioate at room temperature is reported. The results showed that the polymerization is a fast living process, and that the molecular weight of the polymer is as high as 39 600 g mol −1 at 68 % conversion with M w / M n = 1.09 within 68 min. The polymerization rate was markedly influenced by the structures of thiocarbonylthio compounds. Copyright © 2004 Society of Chemical Industry

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