Synthesis, characterization and conformational transitions in copolymers of 2‐( o ‐chlorophenyl)‐4‐methylene‐1,3‐dioxolane with vinyl monomers | Zendy

Morariu Simona | Zendy; Bercea Maria | Zendy

Premium

Synthesis, characterization and conformational transitions in copolymers of 2‐( o ‐chlorophenyl)‐4‐methylene‐1,3‐dioxolane with vinyl monomers

Author(s) -

Morariu Simona,

Bercea Maria

Publication year - 2004

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1503

Subject(s) - copolymer , azobisisobutyronitrile , polymer chemistry , methylene , monomer , polymerization , dioxolane , methyl methacrylate , styrene , glass transition , materials science , methacrylate , chemistry , polymer , organic chemistry

Copolymers of 2‐( o ‐chlorophenyl)‐4‐methylene‐1,3‐dioxolane with methyl methacrylate and styrene were synthesized in benzene at 85 °C in the presence of 2,2′‐azobisisobutyronitrile as initiator. The structure of the resulting copolymers was investigated and a polymerization mechanism was proposed. The intrinsic viscosity of the copolymers in dilute solutions of carbon tetrachloride was determined as a function of temperature and conformational transitions were investigated. Copyright © 2004 Society of Chemical Industry

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research