Synthesis of new open‐chain alkoxyamines and their evaluation for nitroxide‐mediated radical polymerization | Zendy

Nesvadba Peter | Zendy; Bug Lucienne | Zendy; Sift Rosemarie | Zendy

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Synthesis of new open‐chain alkoxyamines and their evaluation for nitroxide‐mediated radical polymerization

Author(s) -

Nesvadba Peter,

Bug Lucienne,

Sift Rosemarie

Publication year - 2004

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1492

Subject(s) - nitroxide mediated radical polymerization , polymerization , radical polymerization , polymer chemistry , acrylate , living free radical polymerization , reversible addition−fragmentation chain transfer polymerization , chain transfer , living polymerization , chemistry , thermostability , materials science , organic chemistry , monomer , polymer , enzyme

New readily available open‐chain alkoxyamines have been synthesized and evaluated as unimolecular initiators for nitroxide‐mediated radical polymerization of styrene and n ‐butyl acrylate. The observed moderate control of polymerization is explained by the low thermostability of the parent nitroxide. Copyright © 2004 Society of Chemical Industry

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