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Synthesis of new open‐chain alkoxyamines and their evaluation for nitroxide‐mediated radical polymerization
Author(s) -
Nesvadba Peter,
Bug Lucienne,
Sift Rosemarie
Publication year - 2004
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1492
Subject(s) - nitroxide mediated radical polymerization , polymerization , radical polymerization , polymer chemistry , acrylate , living free radical polymerization , reversible addition−fragmentation chain transfer polymerization , chain transfer , living polymerization , chemistry , thermostability , materials science , organic chemistry , monomer , polymer , enzyme
New readily available open‐chain alkoxyamines have been synthesized and evaluated as unimolecular initiators for nitroxide‐mediated radical polymerization of styrene and n ‐butyl acrylate. The observed moderate control of polymerization is explained by the low thermostability of the parent nitroxide. Copyright © 2004 Society of Chemical Industry