Photoinitiated radical polymerization of some substituted tetrahydrophthalimido and maleimidophenyl methacrylates | Zendy

Gryshchuk LYu | Zendy; Vretik LO | Zendy; Syromyatnikov VG | Zendy; Novikova OO | Zendy; Paskal LP | Zendy; Voytekunas VYu | Zendy; Abadie MJM | Zendy

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Photoinitiated radical polymerization of some substituted tetrahydrophthalimido and maleimidophenyl methacrylates

Author(s) -

Gryshchuk LYu,

Vretik LO,

Syromyatnikov VG,

Novikova OO,

Paskal LP,

Voytekunas VYu,

Abadie MJM

Publication year - 2004

Publication title -

polymer international

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.592

H-Index - 105

eISSN - 1097-0126

pISSN - 0959-8103

DOI - 10.1002/pi.1382

Subject(s) - photopolymer , methacrylate , polymer chemistry , differential scanning calorimetry , polymerization , radical polymerization , materials science , acrylate polymer , dimethylformamide , polymer , monomer , chemistry , photochemistry , organic chemistry , acrylate , physics , thermodynamics , solvent

The photopolymerization of some substituted tetrahydrophthalimido and 4‐(maleimido)phenyl methacrylates in N , N ‐dimethylformamide solutions was investigated by photo‐differential scanning calorimetry at ambient temperature. Auto‐acceleration of photopolymerization and the formation of cross‐linked products were observed as a result of temperature increases up to 60–80 °C. Substituted 4‐(maleimido)phenyl methacrylates demonstrated higher cross‐linking abilities at elevated temperatures than tetrahydrophthalimidophenyl methacrylates. Copyright © 2003 Society of Chemical Industry

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