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Photoinitiated radical polymerization of some substituted tetrahydrophthalimido and maleimidophenyl methacrylates
Author(s) -
Gryshchuk LYu,
Vretik LO,
Syromyatnikov VG,
Novikova OO,
Paskal LP,
Voytekunas VYu,
Abadie MJM
Publication year - 2004
Publication title -
polymer international
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.592
H-Index - 105
eISSN - 1097-0126
pISSN - 0959-8103
DOI - 10.1002/pi.1382
Subject(s) - photopolymer , methacrylate , polymer chemistry , differential scanning calorimetry , polymerization , radical polymerization , materials science , acrylate polymer , dimethylformamide , polymer , monomer , chemistry , photochemistry , organic chemistry , acrylate , physics , thermodynamics , solvent
The photopolymerization of some substituted tetrahydrophthalimido and 4‐(maleimido)phenyl methacrylates in N , N ‐dimethylformamide solutions was investigated by photo‐differential scanning calorimetry at ambient temperature. Auto‐acceleration of photopolymerization and the formation of cross‐linked products were observed as a result of temperature increases up to 60–80 °C. Substituted 4‐(maleimido)phenyl methacrylates demonstrated higher cross‐linking abilities at elevated temperatures than tetrahydrophthalimidophenyl methacrylates. Copyright © 2003 Society of Chemical Industry