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Development of polymer blend morphology during compounding in a twin‐screw extruder. Part IV: A new computational model with coalescence
Author(s) -
Huneault M. A.,
Shi Z. H.,
Utracki L. A.
Publication year - 1995
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760350114
Subject(s) - breakup , plastics extrusion , materials science , coalescence (physics) , drop (telecommunication) , rheology , mechanics , capillary action , supercritical fluid , pressure drop , polymer , composite material , mechanical engineering , thermodynamics , physics , astrobiology , engineering
In Part II of this series of publications, the first generation model of morphology evolution during polymer blending in a twin‐screw extruder was presented. The model was based on a simplified flow analysis, and an assumption that dispersion occurs via drop fibrillation followed by disintegration. In the present Part IV, several modifications of the model are discussed. (i) The flow analysis was refined by computing the pressure profiles. (ii) The flow paths and strain history of the dispersed droplets within the screw elements are computed directly, which makes it possible to determine the drop susceptibility to deformation and break. (iii) Besides the fibrillation mechanism, a drop‐splitting mechanism for low supercritical capillary numbers is incorporated. (iv) The choice of breakup mechanism is based on micro‐rheological criteria. (v) The coalescence effects are taken into account. (vi) The theoretical model is self‐consistent, without adjustable parameters. The validity of theoretical assumptions was evaluated by comparing the model predictions with the experimental droplet diameters at different positions in the twin‐screw extruder.