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Polymer‐polymer interdiffusion during coextrusion
Author(s) -
Kim Jin Kon,
Han Chang Dae
Publication year - 1991
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760310409
Subject(s) - materials science , polymer , composite material , adhesive , diffusion , dispersity , layer (electronics) , polymer chemistry , thermodynamics , physics
Polymer‐polymer interdiffusion during coextrusion is considered theoretically from the point of view of interdiffusion between two melt streams flowing side by side in a film or sheet coextrusion die. It has been found that three factors, namely, molecular weight, the interaction parameter, and polydispersity have a profound influence on the interfacial layer thickness and adhesive bond strength of coextruded films and sheets. It is pointed out that when interdiffusion between two chemically dissimilar polymers takes place In stratified two‐phase flow, the chain orientation in the flow channel greatly influences the rate of interdiffusion, and consequently the interfacial layer thickness and adhesive bond strength. Orientation factors for macromolecular chains in a steady shear flow field are expressed in terms of shear stress at the interface and the plateau modulus of each of the respective polymers being coextruded. As an illustration, we have used information on the self‐diffusion coefficients for poly(vinylidene fluoride) and poly(methyl methacrylate) in the molten state, to estimate the interfacial layer thickness and adhesive bond strength of coextruded two‐layer sheets, as affected by processing variables.