Premium
The polymerization of a phenolformaldehyde resin in a porous glasswool composite
Author(s) -
Järvelä Pentti K.,
Törmälä Pertti,
Purola Jaakko,
Järvelä Pirkko
Publication year - 1986
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760260602
Subject(s) - materials science , polymerization , composite number , composite material , porosity , curing (chemistry) , degree of polymerization , polymer
The polymerization of the phenolformaldehyde matrix material of porous glass fiber composites is of vital importance in the production of the composite; it also has an, essential effect on the strength properties of the composite, which correlate directly with the degree of polymerization. With a certain material combination, the optimal strength properties can be obtained by a suitable thermal treatment, which depends on the kinetics of the polymerization process. In this study we found that the highest strength values of the composite are obtained by making the polymerization (curing) rapid at a very high temperature using resins with a high degree of polymerization and a high dry matter content. As regards the structure of the composite, the factors that affect the polymerization process arc density, resin content, and thickness. The results obtained with this kind of a composite are valid within a density region of 600 to 1500 kg/m 3 . At lower densities, the polymerization process changes, since thermal convection plays a greater role, and at higher densities the insulating effect of porosity begins to decrease.