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The interpretation of dynamic mechanical behavior in ultra high modulus polymers
Author(s) -
Gibson A. G.,
Davies G. R.,
Ward I. M.
Publication year - 1980
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.760201405
Subject(s) - materials science , interpretation (philosophy) , polymer , composite material , dynamic modulus , modulus , dynamic mechanical analysis , polymer science , computer science , programming language
Recent studies of the dynamic mechanical behavior of ultra high modulus polyethylene? are discussed in the context of our present understanding of the structure of these materials. In particular, the Takayanagi model is shown to achieve a new status in the light of direct measurements of crystal continuity from wide angle X‐ray diffraction data. It is further shown that the Takayanagi model in one formulation is compatible with the Cox model for a short fiber reinforced composite. The fiber composite model offers a simple physical understanding of the fall in modulus due to the α‐relaxation in terms of shear lag. This reduces the effectiveness of the continuous crystal fraction postulated in the Takayanagi model. The γ‐relaxation is considered to be associated primarily with an amorphous relaxation, consistent with the conclusions of previous workers for materials of lower draw ratio.